I have both the 600pf and 800 pf, only just got the 600pf a few weeks ago so it's early days yet. The 800 pf bare is very slightly sharper than the 600 + 1.4x TC but it is a small difference at best to the point that the only reason to use the 800 pf is for the f6.3 v f 9 of the 600 + TC - higher ISO can take the edge off. Having said all that, I generally am more than happy to use the 600 + 1.4x TC where I need to take other lenses with me and thus need less weight and less bulk. If I am only needing one lens on an outing, the 800 pf it is.
Z8 + 600 pf + 1.4x TC in decent light, 1/320s f/9.0 at 840.0mm iso1100
Z8 + 600 pf + 1.4x TC in decent light, 1/250s f/9.0 at 840.0mm iso140
Z8 + 600 pf + 1.4x TC in decent light, 1/500s f/6.3 at 800.0mm iso360
Z8 + 600 pf + 1.4x TC in lower light, 1/160s f/9.0 at 840.0mm iso2200 - underexposed by over a stop to preserve the iridescent blue highlights of the feathers which can blow out very easily.
Z8 + 600 pf + 1.4x TC in lower light, 1/160s f/9.0 at 840.0mm iso2200 - underexposed by over a stop to preserve the iridescent blue highlights of the feathers which can blow out very easily.