Fyi, this morning I had to do the same thing. Use
@JP Onstwedder suggestion to force the "Open With" from Finder first. Then DxO would recognize the .ARW files from LRC and DxO directly. And even after another reboot, 38 files took ~8 minutes to process on my Macbook Pro M3 Max with 36 GB of memory and plenty of interal HD space running Sequoia 15.3.1. Have to say my ancient HP running Win 10 performs better than this now. I guess I'll try another uninstall/re-install of DxO, but not sure I want to rename the LR Catalog just yet. Still waiting to hear back from DxO.